Rational extended thermodynamics (RET) is the theory that is applicable to nonequilibrium phenomena out of local equilibrium. It is expressed by the hyperbolic system of field equations with local constitutive equations and is strictly related to the kinetic theory with the closure method of the hierarchies of moment equations. The book intends to present, in a systematic way, new results obtained by RET of gases in both classical and relativistic cases, and it is a natural continuation of the book " " by the same authors published in 2015. However, this book addresses much wider topics than those of the previous book. Its contents are as follows: RET of rarefied monatomic gases and of polyatomic gases; a simplified RET theory with 6 fields being valid far from equilibrium; RET where both molecular rotational and vibrational modes exist; mixture of gases with multi-temperature. The theory is applied to several typical topics (sound waves, shock waves, etc.) and is compared with experimental data. From a mathematical point of view, RET can be regarded as a theory of hyperbolic symmetric systems, of which it is possible to conduct a qualitative analysis. The book represents a valuable resource for applied mathematicians, physicists, and engineers, offering powerful models for many potential applications such as reentering satellites into the atmosphere, semiconductors, and nanoscale phenomena.