The monograph is devoted to synthesis of new polymers, establishment of basic regularities of obtaining copolymers based on methyl methacrylate (MMA) with butyl methacrylate (BMA), methyl methacrylate with acrylic acid (AA), terpolymer based on methyl methacrylate, 2 - ethylhexyl acrylate (2-EHA) and methacrylic acid (MAA) in the presence of DAK by radical copolymerization. In this connection, the solution of the problem of obtaining environmentally safe quick-drying solvent-free paints (not containing organic solvents) with improved performance characteristics of industrial purpose is relevant in the field of creation of paint and varnish materials. In Kazakhstan due to the sharply continental type of climate and complex hydrogeological situation, waterproofing protection of buildings and structures is a necessary measure. In this regard, the development of waterproofing paint and varnish coatings is relevant. Co- and terpolymers were used for preparation of syrups and paints, then their physical and mechanical properties and their influence on the properties of paints were studied.